data_NGM
# 
_chem_comp.id                                    NGM 
_chem_comp.name                                  NOGALAMYCIN 
_chem_comp.type                                  NON-POLYMER 
_chem_comp.pdbx_type                             HETAD 
_chem_comp.formula                               "C39 H49 N O16" 
_chem_comp.mon_nstd_parent_comp_id               ? 
_chem_comp.pdbx_synonyms                         ? 
_chem_comp.pdbx_formal_charge                    0 
_chem_comp.pdbx_initial_date                     1999-07-08 
_chem_comp.pdbx_modified_date                    2008-10-14 
_chem_comp.pdbx_ambiguous_flag                   N 
_chem_comp.pdbx_release_status                   REL 
_chem_comp.pdbx_replaced_by                      ? 
_chem_comp.pdbx_replaces                         ? 
_chem_comp.formula_weight                        787.803 
_chem_comp.one_letter_code                       ? 
_chem_comp.three_letter_code                     NGM 
_chem_comp.pdbx_model_coordinates_details        ? 
_chem_comp.pdbx_model_coordinates_missing_flag   N 
_chem_comp.pdbx_ideal_coordinates_details        ? 
_chem_comp.pdbx_ideal_coordinates_missing_flag   N 
_chem_comp.pdbx_model_coordinates_db_code        245D 
_chem_comp.pdbx_subcomponent_list                ? 
_chem_comp.pdbx_processing_site                  EBI 
# 
loop_
_chem_comp_atom.comp_id 
_chem_comp_atom.atom_id 
_chem_comp_atom.alt_atom_id 
_chem_comp_atom.type_symbol 
_chem_comp_atom.charge 
_chem_comp_atom.pdbx_align 
_chem_comp_atom.pdbx_aromatic_flag 
_chem_comp_atom.pdbx_leaving_atom_flag 
_chem_comp_atom.pdbx_stereo_config 
_chem_comp_atom.model_Cartn_x 
_chem_comp_atom.model_Cartn_y 
_chem_comp_atom.model_Cartn_z 
_chem_comp_atom.pdbx_model_Cartn_x_ideal 
_chem_comp_atom.pdbx_model_Cartn_y_ideal 
_chem_comp_atom.pdbx_model_Cartn_z_ideal 
_chem_comp_atom.pdbx_component_atom_id 
_chem_comp_atom.pdbx_component_comp_id 
_chem_comp_atom.pdbx_ordinal 
NGM C1    C1   C 0 1 Y N N 19.286 3.175 20.436 0.095  -0.947 -4.589 C1    NGM 1   
NGM C2    C2   C 0 1 Y N N 18.573 2.398 21.382 1.310  -1.067 -5.257 C2    NGM 2   
NGM C3    C3   C 0 1 Y N N 17.631 1.474 20.960 2.483  -1.241 -4.554 C3    NGM 3   
NGM C4    C4   C 0 1 Y N N 17.457 1.269 19.568 2.474  -1.313 -3.162 C4    NGM 4   
NGM C5    C5   C 0 1 N N N 17.828 1.866 17.178 1.244  -1.233 -0.999 C5    NGM 5   
NGM C6    C6   C 0 1 Y N N 18.230 2.682 14.835 0.047  -0.541 1.083  C6    NGM 6   
NGM C7    C7   C 0 1 N N S 18.508 3.411 12.374 -1.018 0.137  3.222  C7    NGM 7   
NGM C8    C8   C 0 1 N N N 19.546 4.086 11.386 -2.201 0.974  3.704  C8    NGM 8   
NGM C9    C9   C 0 1 N N S 20.109 5.473 11.956 -3.492 0.317  3.201  C9    NGM 9   
NGM C10   C10  C 0 1 N N R 20.895 5.112 13.318 -3.565 0.498  1.687  C10   NGM 10  
NGM C11   C11  C 0 1 Y N N 20.237 4.383 15.704 -2.315 -0.200 -0.335 C11   NGM 11  
NGM C12   C12  C 0 1 N N N 19.890 3.739 18.070 -1.200 -0.872 -2.460 C12   NGM 12  
NGM C13   C13  C 0 1 N N N 19.062 6.522 12.170 -4.700 0.986  3.859  C13   NGM 13  
NGM C14   C14  C 0 1 N N N 22.258 4.447 13.161 -4.710 -0.317 1.144  C14   NGM 14  
NGM C15   C15  C 0 1 N N N 24.645 4.983 13.351 -7.024 -0.547 0.474  C15   NGM 15  
NGM C16   C16  C 0 1 Y N N 19.093 2.989 19.062 0.075  -0.998 -3.190 C16   NGM 16  
NGM C17   C17  C 0 1 Y N N 18.146 2.019 18.619 1.275  -1.173 -2.473 C17   NGM 17  
NGM C18   C18  C 0 1 Y N N 18.563 2.694 16.202 0.028  -0.777 -0.290 C18   NGM 18  
NGM C19   C19  C 0 1 Y N N 18.956 3.459 13.897 -1.113 -0.110 1.739  C19   NGM 19  
NGM C20   C20  C 0 1 Y N N 19.943 4.323 14.334 -2.283 0.049  1.035  C20   NGM 20  
NGM C21   C21  C 0 1 Y N N 19.543 3.601 16.631 -1.173 -0.610 -1.005 C21   NGM 21  
NGM C22   C22  C 0 1 N N N 18.661 1.506 23.842 2.364  -1.991 -7.321 C22   NGM 22  
NGM C23   C23  C 0 1 N N N 16.556 7.305 22.164 0.642  2.940  -8.202 C23   NGM 23  
NGM C24   C24  C 0 1 N N N 16.953 6.692 24.407 0.300  3.672  -5.987 C24   NGM 24  
NGM C25   C25  C 0 1 N N N 16.644 4.226 7.966  0.515  -1.685 6.519  C25   NGM 25  
NGM C26   C26  C 0 1 N N N 13.523 6.078 8.032  1.088  1.783  9.121  C26   NGM 26  
NGM C27   C27  C 0 1 N N N 12.409 5.327 12.251 3.605  -1.625 7.199  C27   NGM 27  
NGM C28   C28  C 0 1 N N N 15.085 6.184 11.536 3.949  0.986  6.681  C28   NGM 28  
NGM C29   C29  C 0 1 N N N 13.602 1.611 12.139 2.816  1.773  3.015  C29   NGM 29  
NGM C30   C30  C 0 1 N N S 20.276 4.446 22.332 -0.861 -0.416 -6.586 C30   NGM 30  
NGM C31   C31  C 0 1 N N S 19.237 5.466 22.791 -0.593 1.063  -6.776 C31   NGM 31  
NGM C32   C32  C 0 1 N N R 17.770 5.132 22.600 0.839  1.417  -6.413 C32   NGM 32  
NGM C33   C33  C 0 1 N N R 17.734 3.811 23.381 1.775  0.448  -7.151 C33   NGM 33  
NGM C34   C34  C 0 1 N N R 18.668 2.683 22.975 1.363  -0.979 -6.760 C34   NGM 34  
NGM "C1'" C1*  C 0 1 N N R 16.171 3.199 11.520 0.729  0.263  4.704  "C1'" NGM 35  
NGM "C2'" C2*  C 0 1 N N R 14.740 3.700 11.741 2.089  0.894  5.006  "C2'" NGM 36  
NGM "C3'" C3*  C 0 1 N N R 14.435 4.980 10.993 2.669  0.254  6.275  "C3'" NGM 37  
NGM "C4'" C4*  C 0 1 N N S 14.815 4.789 9.526  1.630  0.369  7.397  "C4'" NGM 38  
NGM "C5'" C5*  C 0 1 N N S 16.232 4.347 9.359  0.304  -0.222 6.914  "C5'" NGM 39  
NGM N1    N1   N 0 1 N N N 16.766 6.143 23.038 1.132  2.797  -6.824 N1    NGM 40  
NGM O1    O1   O 0 1 N N N 20.164 4.152 20.927 -1.072 -0.793 -5.249 O1    NGM 41  
NGM O2    O2   O 0 1 N N N 19.955 3.333 23.172 0.057  -1.237 -7.278 O2    NGM 42  
NGM O4    O4   O 0 1 N N N 16.631 0.204 19.159 3.634  -1.484 -2.481 O4    NGM 43  
NGM O5    O5   O 0 1 N N N 16.989 0.979 16.779 2.206  -1.646 -0.380 O5    NGM 44  
NGM O6    O6   O 0 1 N N N 17.260 1.812 14.331 1.192  -0.731 1.785  O6    NGM 45  
NGM O7    O7   O 0 1 N N N 17.183 3.938 12.229 0.197  0.832  3.506  O7    NGM 46  
NGM O9    O9   O 0 1 N N N 21.122 5.906 10.991 -3.480 -1.075 3.520  O9    NGM 47  
NGM O10   O10  O 0 1 N N N 23.218 5.179 13.522 -5.922 0.239  0.997  O10   NGM 48  
NGM O14   O14  O 0 1 N N N 22.271 3.279 12.731 -4.536 -1.474 0.841  O14   NGM 49  
NGM O12   O12  O 0 1 N N N 20.889 4.459 18.362 -2.259 -0.981 -3.047 O12   NGM 50  
NGM O15   O15  O 0 1 N N N 19.484 6.640 22.018 -1.486 1.803  -5.941 O15   NGM 51  
NGM O16   O16  O 0 1 N N N 16.369 3.381 23.235 3.128  0.687  -6.760 O16   NGM 52  
NGM "O1'" O1*  O 0 1 N N N 16.449 3.123 10.099 -0.168 0.509  5.785  "O1'" NGM 53  
NGM "O2'" O2*  O 0 1 N N N 13.897 2.684 11.206 2.976  0.669  3.908  "O2'" NGM 54  
NGM "O3'" O3*  O 0 1 N N N 13.017 5.190 10.956 2.958  -1.123 6.028  "O3'" NGM 55  
NGM "O4'" O4*  O 0 1 N N N 14.675 6.081 8.927  1.444  1.744  7.737  "O4'" NGM 56  
NGM H3    H3   H 0 1 N N N 17.039 0.919 21.707 3.418  -1.322 -5.088 H3    NGM 57  
NGM H7    H7   H 0 1 N N N 18.491 2.338 12.069 -1.016 -0.818 3.747  H7    NGM 58  
NGM H81   1H8  H 0 1 N N N 20.376 3.386 11.134 -2.207 1.009  4.793  H81   NGM 59  
NGM H82   2H8  H 0 1 N N N 19.108 4.215 10.368 -2.123 1.985  3.303  H82   NGM 60  
NGM H10   H10  H 0 1 N N N 21.159 6.102 13.756 -3.735 1.551  1.458  H10   NGM 61  
NGM H11   H11  H 0 1 N N N 21.031 5.060 16.060 -3.238 -0.073 -0.880 H11   NGM 62  
NGM H131  1H13 H 0 0 N N N 19.453 7.487 12.566 -4.634 0.872  4.941  H131  NGM 63  
NGM H132  2H13 H 0 0 N N N 18.484 6.692 11.231 -4.712 2.046  3.606  H132  NGM 64  
NGM H133  3H13 H 0 0 N N N 18.249 6.132 12.826 -5.616 0.517  3.500  H133  NGM 65  
NGM H151  1H15 H 0 0 N N N 25.494 5.630 13.670 -7.921 0.070  0.427  H151  NGM 66  
NGM H152  2H15 H 0 0 N N N 24.857 3.982 13.793 -6.775 -0.902 -0.525 H152  NGM 67  
NGM H153  3H15 H 0 0 N N N 24.789 4.829 12.256 -7.204 -1.400 1.128  H153  NGM 68  
NGM H221  1H22 H 0 0 N N N 18.726 1.702 24.937 2.060  -2.998 -7.036 H221  NGM 69  
NGM H222  2H22 H 0 0 N N N 17.763 0.881 23.623 2.390  -1.912 -8.407 H222  NGM 70  
NGM H223  3H22 H 0 0 N N N 19.472 0.806 23.534 3.355  -1.783 -6.918 H223  NGM 71  
NGM H231  1H23 H 0 0 N N N 16.415 6.893 21.137 1.000  3.881  -8.619 H231  NGM 72  
NGM H232  2H23 H 0 0 N N N 15.722 7.967 22.496 1.010  2.110  -8.806 H232  NGM 73  
NGM H233  3H23 H 0 0 N N N 17.368 8.066 22.231 -0.447 2.934  -8.202 H233  NGM 74  
NGM H241  1H24 H 0 0 N N N 17.112 5.810 25.070 0.624  4.706  -6.108 H241  NGM 75  
NGM H242  2H24 H 0 0 N N N 17.765 7.453 24.474 -0.742 3.581  -6.290 H242  NGM 76  
NGM H243  3H24 H 0 0 N N N 16.119 7.354 24.739 0.402  3.379  -4.942 H243  NGM 77  
NGM H251  1H25 H 0 0 N N N 17.701 3.896 7.841  0.881  -2.245 7.379  H251  NGM 78  
NGM H252  2H25 H 0 0 N N N 15.952 3.553 7.407  -0.431 -2.111 6.184  H252  NGM 79  
NGM H253  3H25 H 0 0 N N N 16.460 5.178 7.416  1.244  -1.742 5.711  H253  NGM 80  
NGM H261  1H26 H 0 0 N N N 13.413 7.084 7.565  0.934  2.817  9.428  H261  NGM 81  
NGM H262  2H26 H 0 0 N N N 13.581 5.264 7.271  0.168  1.218  9.275  H262  NGM 82  
NGM H263  3H26 H 0 0 N N N 12.590 5.748 8.546  1.888  1.342  9.715  H263  NGM 83  
NGM H271  1H27 H 0 0 N N N 11.306 5.490 12.222 3.781  -2.695 7.086  H271  NGM 84  
NGM H272  2H27 H 0 0 N N N 12.657 4.450 12.893 4.558  -1.113 7.335  H272  NGM 85  
NGM H273  3H27 H 0 0 N N N 12.908 6.136 12.833 2.971  -1.450 8.068  H273  NGM 86  
NGM H281  1H28 H 0 0 N N N 14.860 7.126 10.985 4.722  0.808  5.933  H281  NGM 87  
NGM H282  2H28 H 0 0 N N N 14.838 6.301 12.617 3.750  2.056  6.750  H282  NGM 88  
NGM H283  3H28 H 0 0 N N N 16.187 6.030 11.603 4.288  0.617  7.649  H283  NGM 89  
NGM H291  1H29 H 0 0 N N N 12.942 0.815 11.720 3.476  1.645  2.157  H291  NGM 90  
NGM H292  2H29 H 0 0 N N N 14.544 1.168 12.537 1.782  1.819  2.675  H292  NGM 91  
NGM H293  3H29 H 0 0 N N N 13.172 2.019 13.083 3.070  2.698  3.533  H293  NGM 92  
NGM H30   H30  H 0 1 N N N 21.334 4.784 22.426 -1.817 -0.591 -7.079 H30   NGM 93  
NGM H31   H31  H 0 1 N N N 19.366 5.541 23.895 -0.775 1.326  -7.818 H31   NGM 94  
NGM H32   H32  H 0 1 N N N 17.458 5.088 21.530 0.982  1.317  -5.337 H32   NGM 95  
NGM H33   H33  H 0 1 N N N 18.099 4.023 24.412 1.671  0.582  -8.227 H33   NGM 96  
NGM "H1'" H1*  H 0 1 N N N 16.222 2.177 11.965 0.850  -0.812 4.571  "H1'" NGM 97  
NGM "H2'" H2*  H 0 1 N N N 14.589 3.908 12.826 1.967  1.966  5.162  "H2'" NGM 98  
NGM "H4'" H4*  H 0 1 N N N 14.170 4.004 9.065  1.977  -0.179 8.273  "H4'" NGM 99  
NGM "H5'" H5*  H 0 1 N N N 16.884 5.147 9.779  -0.430 -0.166 7.717  "H5'" NGM 100 
NGM HO4   HO4  H 0 1 N N N 16.514 0.066 18.226 3.980  -0.601 -2.292 HO4   NGM 101 
NGM HO6   HO6  H 0 1 N N N 17.035 1.803 13.408 1.667  0.111  1.777  HO6   NGM 102 
NGM HO9   HO9  H 0 1 N N N 21.455 6.728 11.329 -3.415 -1.140 4.483  HO9   NGM 103 
NGM H15   H15  H 0 1 N N N 18.837 7.274 22.303 -2.383 1.553  -6.201 H15   NGM 104 
NGM H16   H16  H 0 1 N N N 16.346 2.563 23.718 3.320  1.612  -6.966 H16   NGM 105 
# 
loop_
_chem_comp_bond.comp_id 
_chem_comp_bond.atom_id_1 
_chem_comp_bond.atom_id_2 
_chem_comp_bond.value_order 
_chem_comp_bond.pdbx_aromatic_flag 
_chem_comp_bond.pdbx_stereo_config 
_chem_comp_bond.pdbx_ordinal 
NGM C1    C2    DOUB Y N 1   
NGM C1    C16   SING Y N 2   
NGM C1    O1    SING N N 3   
NGM C2    C3    SING Y N 4   
NGM C2    C34   SING N N 5   
NGM C3    C4    DOUB Y N 6   
NGM C3    H3    SING N N 7   
NGM C4    C17   SING Y N 8   
NGM C4    O4    SING N N 9   
NGM C5    C17   SING N N 10  
NGM C5    C18   SING N N 11  
NGM C5    O5    DOUB N N 12  
NGM C6    C18   DOUB Y N 13  
NGM C6    C19   SING Y N 14  
NGM C6    O6    SING N N 15  
NGM C7    C8    SING N N 16  
NGM C7    C19   SING N N 17  
NGM C7    O7    SING N N 18  
NGM C7    H7    SING N N 19  
NGM C8    C9    SING N N 20  
NGM C8    H81   SING N N 21  
NGM C8    H82   SING N N 22  
NGM C9    C10   SING N N 23  
NGM C9    C13   SING N N 24  
NGM C9    O9    SING N N 25  
NGM C10   C14   SING N N 26  
NGM C10   C20   SING N N 27  
NGM C10   H10   SING N N 28  
NGM C11   C20   SING Y N 29  
NGM C11   C21   DOUB Y N 30  
NGM C11   H11   SING N N 31  
NGM C12   C16   SING N N 32  
NGM C12   C21   SING N N 33  
NGM C12   O12   DOUB N N 34  
NGM C13   H131  SING N N 35  
NGM C13   H132  SING N N 36  
NGM C13   H133  SING N N 37  
NGM C14   O10   SING N N 38  
NGM C14   O14   DOUB N N 39  
NGM C15   O10   SING N N 40  
NGM C15   H151  SING N N 41  
NGM C15   H152  SING N N 42  
NGM C15   H153  SING N N 43  
NGM C16   C17   DOUB Y N 44  
NGM C18   C21   SING Y N 45  
NGM C19   C20   DOUB Y N 46  
NGM C22   C34   SING N N 47  
NGM C22   H221  SING N N 48  
NGM C22   H222  SING N N 49  
NGM C22   H223  SING N N 50  
NGM C23   N1    SING N N 51  
NGM C23   H231  SING N N 52  
NGM C23   H232  SING N N 53  
NGM C23   H233  SING N N 54  
NGM C24   N1    SING N N 55  
NGM C24   H241  SING N N 56  
NGM C24   H242  SING N N 57  
NGM C24   H243  SING N N 58  
NGM C25   "C5'" SING N N 59  
NGM C25   H251  SING N N 60  
NGM C25   H252  SING N N 61  
NGM C25   H253  SING N N 62  
NGM C26   "O4'" SING N N 63  
NGM C26   H261  SING N N 64  
NGM C26   H262  SING N N 65  
NGM C26   H263  SING N N 66  
NGM C27   "O3'" SING N N 67  
NGM C27   H271  SING N N 68  
NGM C27   H272  SING N N 69  
NGM C27   H273  SING N N 70  
NGM C28   "C3'" SING N N 71  
NGM C28   H281  SING N N 72  
NGM C28   H282  SING N N 73  
NGM C28   H283  SING N N 74  
NGM C29   "O2'" SING N N 75  
NGM C29   H291  SING N N 76  
NGM C29   H292  SING N N 77  
NGM C29   H293  SING N N 78  
NGM C30   C31   SING N N 79  
NGM C30   O1    SING N N 80  
NGM C30   O2    SING N N 81  
NGM C30   H30   SING N N 82  
NGM C31   C32   SING N N 83  
NGM C31   O15   SING N N 84  
NGM C31   H31   SING N N 85  
NGM C32   C33   SING N N 86  
NGM C32   N1    SING N N 87  
NGM C32   H32   SING N N 88  
NGM C33   C34   SING N N 89  
NGM C33   O16   SING N N 90  
NGM C33   H33   SING N N 91  
NGM C34   O2    SING N N 92  
NGM "C1'" "C2'" SING N N 93  
NGM "C1'" O7    SING N N 94  
NGM "C1'" "O1'" SING N N 95  
NGM "C1'" "H1'" SING N N 96  
NGM "C2'" "C3'" SING N N 97  
NGM "C2'" "O2'" SING N N 98  
NGM "C2'" "H2'" SING N N 99  
NGM "C3'" "C4'" SING N N 100 
NGM "C3'" "O3'" SING N N 101 
NGM "C4'" "C5'" SING N N 102 
NGM "C4'" "O4'" SING N N 103 
NGM "C4'" "H4'" SING N N 104 
NGM "C5'" "O1'" SING N N 105 
NGM "C5'" "H5'" SING N N 106 
NGM O4    HO4   SING N N 107 
NGM O6    HO6   SING N N 108 
NGM O9    HO9   SING N N 109 
NGM O15   H15   SING N N 110 
NGM O16   H16   SING N N 111 
# 
loop_
_pdbx_chem_comp_descriptor.comp_id 
_pdbx_chem_comp_descriptor.type 
_pdbx_chem_comp_descriptor.program 
_pdbx_chem_comp_descriptor.program_version 
_pdbx_chem_comp_descriptor.descriptor 
NGM SMILES           ACDLabs              10.04 O=C(OC)C7c4c(c(O)c5C(=O)c3c(O)cc1c(OC2OC1(C(O)C(N(C)C)C2O)C)c3C(=O)c5c4)C(OC6OC(C)C(OC)C(OC)(C)C6OC)CC7(O)C 
NGM InChI            InChI                1.02b 
;InChI=1/C39H49NO16/c1-14-32(49-7)39(4,52-10)33(50-8)36(53-14)54-19-13-37(2,48)24(34(47)51-9)15-11-16-21(27(43)20(15)19)28(44)22-18(41)12-17-30(23(22)26(16)42)55-35-29(45)25(40(5)6)31(46)38(17,3)56-35/h11-12,14,19,24-25,29,31-33,35-36,41,43,45-46,48H,13H2,1-10H3/t14-,19-,24-,25-,29-,31+,32-,33-,35+,36-,37-,38+,39+/m0/s1
;
NGM InChIKey         InChI                1.02b KGTDRFCXGRULNK-JYOBTZKQBE 
NGM SMILES_CANONICAL CACTVS               3.341 CO[C@H]1[C@H](C)O[C@@H](O[C@H]2C[C@](C)(O)[C@H](C(=O)OC)c3cc4C(=O)c5c6O[C@@H]7O[C@@](C)([C@H](O)[C@H]([C@@H]7O)N(C)C)c6cc(O)c5C(=O)c4c(O)c23)[C@H](OC)[C@]1(C)OC 
NGM SMILES           CACTVS               3.341 CO[CH]1[CH](C)O[CH](O[CH]2C[C](C)(O)[CH](C(=O)OC)c3cc4C(=O)c5c6O[CH]7O[C](C)([CH](O)[CH]([CH]7O)N(C)C)c6cc(O)c5C(=O)c4c(O)c23)[CH](OC)[C]1(C)OC 
NGM SMILES_CANONICAL "OpenEye OEToolkits" 1.5.0 C[C@H]1[C@@H]([C@@]([C@H]([C@@H](O1)O[C@H]2C[C@]([C@@H](c3c2c(c4c(c3)C(=O)c5c(c(cc6c5O[C@H]7[C@H]([C@@H]([C@H]([C@@]6(O7)C)O)N(C)C)O)O)C4=O)O)C(=O)OC)(C)O)OC)(C)OC)OC 
NGM SMILES           "OpenEye OEToolkits" 1.5.0 CC1C(C(C(C(O1)OC2CC(C(c3c2c(c4c(c3)C(=O)c5c(c(cc6c5OC7C(C(C(C6(O7)C)O)N(C)C)O)O)C4=O)O)C(=O)OC)(C)O)OC)(C)OC)OC 
# 
_pdbx_chem_comp_identifier.comp_id           NGM 
_pdbx_chem_comp_identifier.type              "SYSTEMATIC NAME" 
_pdbx_chem_comp_identifier.program           ACDLabs 
_pdbx_chem_comp_identifier.program_version   10.04 
_pdbx_chem_comp_identifier.identifier        
;methyl (2R,3S,4R,5R,6R,11S,13S,14R)-11-[(6-deoxy-3-C-methyl-2,3,4-tri-O-methyl-alpha-L-mannopyranosyl)oxy]-4-(dimethylamino)-3,5,8,10,13-pentahydroxy-6,13-dimethyl-9,16-dioxo-3,4,5,6,9,11,12,13,14,16-decahydro-2H-2,6-epoxytetraceno[1,2-b]oxocine-14-carboxylate
;
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