data_L4P
# 
_chem_comp.id                                    L4P 
_chem_comp.name                                  3-[GLYCEROLYLPHOSPHONYL]-[1,2-DI-PHYTANYL]GLYCEROL 
_chem_comp.type                                  NON-POLYMER 
_chem_comp.pdbx_type                             HETAIN 
_chem_comp.formula                               "C46 H95 O8 P" 
_chem_comp.mon_nstd_parent_comp_id               ? 
_chem_comp.pdbx_synonyms                         "2,3-DI-O-PHYTANLY-3-SN-GLYCERO-1-PHOSPHORYL-3'-SN-GLYCEROL" 
_chem_comp.pdbx_formal_charge                    0 
_chem_comp.pdbx_initial_date                     1999-09-22 
_chem_comp.pdbx_modified_date                    2008-10-14 
_chem_comp.pdbx_ambiguous_flag                   N 
_chem_comp.pdbx_release_status                   REL 
_chem_comp.pdbx_replaced_by                      ? 
_chem_comp.pdbx_replaces                         ? 
_chem_comp.formula_weight                        807.215 
_chem_comp.one_letter_code                       ? 
_chem_comp.three_letter_code                     L4P 
_chem_comp.pdbx_model_coordinates_details        ? 
_chem_comp.pdbx_model_coordinates_missing_flag   Y 
_chem_comp.pdbx_ideal_coordinates_details        ? 
_chem_comp.pdbx_ideal_coordinates_missing_flag   N 
_chem_comp.pdbx_model_coordinates_db_code        1DZE 
_chem_comp.pdbx_subcomponent_list                ? 
_chem_comp.pdbx_processing_site                  EBI 
# 
loop_
_chem_comp_atom.comp_id 
_chem_comp_atom.atom_id 
_chem_comp_atom.alt_atom_id 
_chem_comp_atom.type_symbol 
_chem_comp_atom.charge 
_chem_comp_atom.pdbx_align 
_chem_comp_atom.pdbx_aromatic_flag 
_chem_comp_atom.pdbx_leaving_atom_flag 
_chem_comp_atom.pdbx_stereo_config 
_chem_comp_atom.model_Cartn_x 
_chem_comp_atom.model_Cartn_y 
_chem_comp_atom.model_Cartn_z 
_chem_comp_atom.pdbx_model_Cartn_x_ideal 
_chem_comp_atom.pdbx_model_Cartn_y_ideal 
_chem_comp_atom.pdbx_model_Cartn_z_ideal 
_chem_comp_atom.pdbx_component_atom_id 
_chem_comp_atom.pdbx_component_comp_id 
_chem_comp_atom.pdbx_ordinal 
L4P C1   C1   C 0 1 N N N 38.049 5.341  12.147 -8.509  18.670 5.393  C1   L4P 1   
L4P C2   C2   C 0 1 N N S 37.871 4.754  10.729 -7.015  18.825 5.644  C2   L4P 2   
L4P C3   C3   C 0 1 N N N 37.295 5.819  9.793  -6.645  20.276 5.929  C3   L4P 3   
L4P C4   C4   C 0 1 N N N 34.026 5.459  6.983  -4.305  22.159 3.909  C4   L4P 4   
L4P C5   C5   C 0 1 N N R 33.182 6.275  6.003  -2.821  22.414 4.152  C5   L4P 5   
L4P C6   C6   C 0 1 N N N 31.829 5.591  5.797  -1.960  21.747 3.087  C6   L4P 6   
L4P O1   O1   O 0 1 N N N 38.357 4.293  13.085 -8.790  17.307 5.107  O1   L4P 7   
L4P O2   O2   O 0 1 N N N 39.139 4.360  10.199 -6.674  18.032 6.784  O2   L4P 8   
L4P O3   O3   O 0 1 N N N 36.577 5.182  8.730  -6.993  21.091 4.815  O3   L4P 9   
L4P O4   O4   O 0 1 N N N 35.328 5.256  6.421  -5.072  22.789 4.920  O4   L4P 10  
L4P O5   O5   O 0 1 N N N 32.974 7.580  6.539  -2.582  23.823 4.093  O5   L4P 11  
L4P O6   O6   O 0 1 N N N ?      ?      ?      -0.592  22.042 3.348  O6   L4P 12  
L4P O1P  O1P  O 0 1 N N N 37.850 5.226  6.536  -7.380  23.388 6.028  O1P  L4P 13  
L4P O2P  O2P  O 0 1 N N N 36.680 7.226  7.217  -7.105  23.204 3.429  O2P  L4P 14  
L4P P1   P1   P 0 1 N N S 36.640 5.747  7.215  -6.687  22.676 4.901  P1   L4P 15  
L4P C11  C11  C 0 1 N N N 38.825 4.602  14.409 -10.178 17.096 4.883  C11  L4P 16  
L4P C12  C12  C 0 1 N N N 39.221 3.296  15.119 -10.407 15.619 4.583  C12  L4P 17  
L4P C13  C13  C 0 1 N N R 39.317 3.498  16.644 -11.885 15.264 4.345  C13  L4P 18  
L4P C14  C14  C 0 1 N N N 38.073 4.218  17.176 -12.762 15.618 5.549  C14  L4P 19  
L4P C15  C15  C 0 1 N N N 40.581 4.292  16.997 -12.059 13.785 3.935  C15  L4P 20  
L4P C16  C16  C 0 1 N N N 41.718 3.310  17.314 -11.641 12.757 4.995  C16  L4P 21  
L4P C17  C17  C 0 1 N N N 42.759 3.994  18.213 -11.802 11.326 4.465  C17  L4P 22  
L4P C18  C18  C 0 1 N N R 43.617 2.946  18.955 -11.466 10.237 5.505  C18  L4P 23  
L4P C19  C19  C 0 1 N N N 44.605 2.295  17.977 -9.998  10.303 5.945  C19  L4P 24  
L4P C20  C20  C 0 1 N N N 42.721 1.876  19.616 -11.758 8.820  4.963  C20  L4P 25  
L4P C21  C21  C 0 1 N N N 43.569 0.722  20.190 -11.617 7.668  5.966  C21  L4P 26  
L4P C22  C22  C 0 1 N N N 44.707 1.284  21.055 -12.473 7.781  7.233  C22  L4P 27  
L4P C23  C23  C 0 1 N N R 45.072 0.297  22.171 -13.992 7.915  7.004  C23  L4P 28  
L4P C24  C24  C 0 1 N N N 44.256 0.649  23.421 -14.702 8.091  8.351  C24  L4P 29  
L4P C25  C25  C 0 1 N N N 46.582 0.424  22.467 -14.613 6.764  6.185  C25  L4P 30  
L4P C26  C26  C 0 1 N N N 46.942 -0.159 23.848 -13.934 6.476  4.840  C26  L4P 31  
L4P C27  C27  C 0 1 N N N 46.571 -1.649 23.906 -14.597 5.286  4.136  C27  L4P 32  
L4P C28  C28  C 0 1 N N N 47.798 -2.492 24.275 -13.976 4.960  2.765  C28  L4P 33  
L4P C29  C29  C 0 1 N N N 47.795 -2.765 25.780 -14.087 6.178  1.844  C29  L4P 34  
L4P C30  C30  C 0 1 N N N 47.727 -3.828 23.529 -12.513 4.528  2.873  C30  L4P 35  
L4P C41  C41  C 0 1 N N N 39.959 3.421  10.889 -5.286  18.107 7.066  C41  L4P 36  
L4P C42  C42  C 0 1 N N N 41.402 3.527  10.378 -4.988  17.245 8.287  C42  L4P 37  
L4P C43  C43  C 0 1 N N R 42.382 2.864  11.368 -3.499  17.228 8.676  C43  L4P 38  
L4P C44  C44  C 0 1 N N N 41.619 2.106  12.467 -2.614  16.716 7.537  C44  L4P 39  
L4P C45  C45  C 0 1 N N N 43.271 3.942  12.002 -3.258  16.436 9.980  C45  L4P 40  
L4P C46  C46  C 0 1 N N N 44.222 3.302  13.022 -3.595  14.941 9.911  C46  L4P 41  
L4P C47  C47  C 0 1 N N N 43.832 3.753  14.433 -3.372  14.265 11.270 C47  L4P 42  
L4P C48  C48  C 0 1 N N R ?      ?      ?      -3.625  12.743 11.256 C48  L4P 43  
L4P C49  C49  C 0 1 N N N ?      ?      ?      -5.083  12.411 10.915 C49  L4P 44  
L4P C50  C50  C 0 1 N N N ?      ?      ?      -3.272  12.093 12.613 C50  L4P 45  
L4P C51  C51  C 0 1 N N N ?      ?      ?      -3.328  10.561 12.664 C51  L4P 46  
L4P C52  C52  C 0 1 N N N ?      ?      ?      -2.448  9.828  11.644 C52  L4P 47  
L4P C53  C53  C 0 1 N N R ?      ?      ?      -0.945  10.166 11.693 C53  L4P 48  
L4P C54  C54  C 0 1 N N N ?      ?      ?      -0.212  9.417  10.574 C54  L4P 49  
L4P C55  C55  C 0 1 N N N ?      ?      ?      -0.284  9.917  13.065 C55  L4P 50  
L4P C56  C56  C 0 1 N N N ?      ?      ?      1.165   10.402 13.192 C56  L4P 51  
L4P C57  C57  C 0 1 N N N ?      ?      ?      1.705   10.151 14.606 C57  L4P 52  
L4P C58  C58  C 0 1 N N N ?      ?      ?      3.168   10.595 14.792 C58  L4P 53  
L4P C59  C59  C 0 1 N N N ?      ?      ?      4.065   9.848  13.802 C59  L4P 54  
L4P C60  C60  C 0 1 N N N ?      ?      ?      3.349   12.103 14.615 C60  L4P 55  
L4P H12  2H1  H 0 1 N N N 38.872 6.071  12.136 -8.831  19.267 4.534  H12  L4P 56  
L4P H11  1H1  H 0 1 N N N 37.113 5.832  12.452 -9.089  18.957 6.276  H11  L4P 57  
L4P H2   H2   H 0 1 N N N 37.195 3.889  10.799 -6.439  18.427 4.800  H2   L4P 58  
L4P H32  2H3  H 0 1 N N N 36.613 6.472  10.357 -5.571  20.390 6.110  H32  L4P 59  
L4P H31  1H3  H 0 1 N N N 38.115 6.420  9.373  -7.192  20.659 6.796  H31  L4P 60  
L4P H42  2H4  H 0 1 N N N 34.115 6.003  7.935  -4.537  21.090 3.924  H42  L4P 61  
L4P H41  1H4  H 0 1 N N N 33.545 4.487  7.167  -4.625  22.577 2.950  H41  L4P 62  
L4P H5   H5   H 0 1 N N N 33.705 6.347  5.038  -2.521  22.085 5.153  H5   L4P 63  
L4P H62  2H6  H 0 1 N N N 32.174 4.982  4.948  -2.201  22.125 2.088  H62  L4P 64  
L4P H61  1H6  H 0 1 N N N 31.546 5.933  6.803  -2.082  20.660 3.106  H61  L4P 65  
L4P H5O  H5O  H 0 1 N N N 32.928 7.530  7.487  -2.780  24.169 4.976  H5O  L4P 66  
L4P H6O  H6O  H 0 1 N N N ?      ?      ?      -0.534  22.283 4.286  H6O  L4P 67  
L4P HOP2 2HOP H 0 0 N N N 36.689 7.542  8.113  -7.144  24.171 3.267  HOP2 L4P 68  
L4P H112 2H11 H 0 0 N N N 39.699 5.268  14.346 -10.718 17.410 5.781  H112 L4P 69  
L4P H111 1H11 H 0 0 N N N 38.028 5.106  14.976 -10.491 17.719 4.039  H111 L4P 70  
L4P H122 2H12 H 0 0 N N N 38.460 2.531  14.908 -9.816  15.349 3.698  H122 L4P 71  
L4P H121 1H12 H 0 0 N N N 40.206 2.980  14.746 -9.991  15.025 5.406  H121 L4P 72  
L4P H13  H13  H 0 1 N N N 39.375 2.508  17.120 -12.242 15.862 3.496  H13  L4P 73  
L4P H143 3H14 H 0 0 N N N 38.183 4.390  18.257 -13.788 15.266 5.402  H143 L4P 74  
L4P H142 2H14 H 0 0 N N N 37.960 5.183  16.660 -12.377 15.176 6.474  H142 L4P 75  
L4P H141 1H14 H 0 0 N N N 37.184 3.597  16.992 -12.810 16.702 5.694  H141 L4P 76  
L4P H152 2H15 H 0 0 N N N 40.868 4.927  16.146 -13.112 13.618 3.672  H152 L4P 77  
L4P H151 1H15 H 0 0 N N N 40.386 4.929  17.872 -11.484 13.605 3.018  H151 L4P 78  
L4P H162 2H16 H 0 0 N N N 41.307 2.432  17.834 -12.252 12.876 5.896  H162 L4P 79  
L4P H161 1H16 H 0 0 N N N 42.198 2.994  16.376 -10.597 12.929 5.274  H161 L4P 80  
L4P H172 2H17 H 0 0 N N N 43.416 4.619  17.590 -11.172 11.195 3.576  H172 L4P 81  
L4P H171 1H17 H 0 0 N N N 42.233 4.610  18.957 -12.841 11.203 4.136  H171 L4P 82  
L4P H18  H18  H 0 1 N N N 44.185 3.452  19.750 -12.080 10.406 6.398  H18  L4P 83  
L4P H193 3H19 H 0 0 N N N 44.112 2.139  17.006 -9.323  10.235 5.085  H193 L4P 84  
L4P H192 2H19 H 0 0 N N N 45.476 2.953  17.844 -9.783  11.234 6.478  H192 L4P 85  
L4P H191 1H19 H 0 0 N N N 44.935 1.326  18.380 -9.759  9.482  6.629  H191 L4P 86  
L4P H202 2H20 H 0 0 N N N 42.152 2.342  20.434 -11.099 8.621  4.108  H202 L4P 87  
L4P H201 1H20 H 0 0 N N N 42.042 1.467  18.854 -12.780 8.794  4.562  H201 L4P 88  
L4P H212 2H21 H 0 0 N N N 42.930 0.074  20.807 -11.857 6.721  5.469  H212 L4P 89  
L4P H211 1H21 H 0 0 N N N 43.999 0.143  19.360 -10.560 7.584  6.247  H211 L4P 90  
L4P H222 2H22 H 0 0 N N N 45.590 1.455  20.422 -12.285 6.905  7.867  H222 L4P 91  
L4P H221 1H22 H 0 0 N N N 44.375 2.229  21.510 -12.112 8.639  7.814  H221 L4P 92  
L4P H23  H23  H 0 1 N N N 44.847 -0.736 21.869 -14.171 8.839  6.439  H23  L4P 93  
L4P H243 3H24 H 0 0 N N N 44.929 0.733  24.287 -15.760 8.329  8.198  H243 L4P 94  
L4P H242 2H24 H 0 0 N N N 43.739 1.607  23.264 -14.651 7.182  8.959  H242 L4P 95  
L4P H241 1H24 H 0 0 N N N 43.514 -0.141 23.609 -14.257 8.912  8.923  H241 L4P 96  
L4P H252 2H25 H 0 0 N N N 47.141 -0.125 21.695 -15.671 6.997  6.004  H252 L4P 97  
L4P H251 1H25 H 0 0 N N N 46.845 1.492  22.465 -14.611 5.850  6.790  H251 L4P 98  
L4P H262 2H26 H 0 0 N N N 48.023 -0.047 24.018 -13.998 7.362  4.201  H262 L4P 99  
L4P H261 1H26 H 0 0 N N N 46.381 0.382  24.624 -12.873 6.254  4.994  H261 L4P 100 
L4P H272 2H27 H 0 0 N N N 45.790 -1.797 24.666 -14.508 4.402  4.782  H272 L4P 101 
L4P H271 1H27 H 0 0 N N N 46.205 -1.965 22.918 -15.670 5.483  4.020  H271 L4P 102 
L4P H28  H28  H 0 1 N N N 48.715 -1.951 23.998 -14.544 4.140  2.307  H28  L4P 103 
L4P H293 3H29 H 0 0 N N N 47.794 -3.851 25.956 -13.686 5.952  0.850  H293 L4P 104 
L4P H292 2H29 H 0 0 N N N 48.692 -2.320 26.235 -15.133 6.478  1.720  H292 L4P 105 
L4P H291 1H29 H 0 0 N N N 46.896 -2.320 26.231 -13.533 7.033  2.247  H291 L4P 106 
L4P H303 3H30 H 0 0 N N N 47.710 -3.643 22.445 -12.080 4.373  1.879  H303 L4P 107 
L4P H302 2H30 H 0 0 N N N 48.607 -4.437 23.783 -11.912 5.284  3.389  H302 L4P 108 
L4P H301 1H30 H 0 0 N N N 46.813 -4.364 23.823 -12.415 3.584  3.418  H301 L4P 109 
L4P H412 2H41 H 0 0 N N N 39.935 3.637  11.967 -4.742  17.756 6.185  H412 L4P 110 
L4P H411 1H41 H 0 0 N N N 39.581 2.404  10.710 -5.027  19.154 7.254  H411 L4P 111 
L4P H422 2H42 H 0 0 N N N 41.477 3.020  9.405  -5.585  17.617 9.130  H422 L4P 112 
L4P H421 1H42 H 0 0 N N N 41.665 4.590  10.278 -5.351  16.227 8.095  H421 L4P 113 
L4P H43  H43  H 0 1 N N N 43.005 2.142  10.819 -3.195  18.263 8.885  H43  L4P 114 
L4P H443 3H44 H 0 0 N N N 42.289 1.925  13.321 -1.574  16.615 7.866  H443 L4P 115 
L4P H442 2H44 H 0 0 N N N 40.759 2.707  12.797 -2.951  15.743 7.168  H442 L4P 116 
L4P H441 1H44 H 0 0 N N N 41.264 1.144  12.069 -2.619  17.413 6.693  H441 L4P 117 
L4P H452 2H45 H 0 0 N N N 43.860 4.437  11.216 -2.204  16.551 10.267 H452 L4P 118 
L4P H451 1H45 H 0 0 N N N 42.636 4.681  12.513 -3.845  16.897 10.784 H451 L4P 119 
L4P H462 2H46 H 0 0 N N N 44.151 2.206  12.954 -2.970  14.449 9.159  H462 L4P 120 
L4P H461 1H46 H 0 0 N N N 45.255 3.615  12.808 -4.639  14.819 9.608  H461 L4P 121 
L4P H472 2H47 H 0 0 N N N 44.154 3.135  15.284 -4.016  14.740 12.021 H472 L4P 122 
L4P H471 1H47 H 0 0 N N N 44.225 4.676  14.885 -2.337  14.457 11.576 H471 L4P 123 
L4P H48  H48  H 0 1 N N N ?      ?      ?      -2.999  12.293 10.476 H48  L4P 124 
L4P H493 3H49 H 0 0 N N N ?      ?      ?      -5.774  12.909 11.603 H493 L4P 125 
L4P H492 2H49 H 0 0 N N N ?      ?      ?      -5.334  12.716 9.895  H492 L4P 126 
L4P H491 1H49 H 0 0 N N N ?      ?      ?      -5.262  11.332 10.977 H491 L4P 127 
L4P H502 2H50 H 0 0 N N N ?      ?      ?      -3.940  12.493 13.386 H502 L4P 128 
L4P H501 1H50 H 0 0 N N N ?      ?      ?      -2.260  12.403 12.905 H501 L4P 129 
L4P H512 2H51 H 0 0 N N N ?      ?      ?      -3.051  10.220 13.669 H512 L4P 130 
L4P H511 1H51 H 0 0 N N N ?      ?      ?      -4.371  10.249 12.534 H511 L4P 131 
L4P H522 2H52 H 0 0 N N N ?      ?      ?      -2.574  8.746  11.780 H522 L4P 132 
L4P H521 1H52 H 0 0 N N N ?      ?      ?      -2.840  10.040 10.641 H521 L4P 133 
L4P H53  H53  H 0 1 N N N ?      ?      ?      -0.828  11.236 11.475 H53  L4P 134 
L4P H543 3H54 H 0 0 N N N ?      ?      ?      0.828   9.753  10.505 H543 L4P 135 
L4P H542 2H54 H 0 0 N N N ?      ?      ?      -0.200  8.336  10.748 H542 L4P 136 
L4P H541 1H54 H 0 0 N N N ?      ?      ?      -0.685  9.602  9.604  H541 L4P 137 
L4P H552 2H55 H 0 0 N N N ?      ?      ?      -0.316  8.839  13.276 H552 L4P 138 
L4P H551 1H55 H 0 0 N N N ?      ?      ?      -0.890  10.389 13.848 H551 L4P 139 
L4P H562 2H56 H 0 0 N N N ?      ?      ?      1.791   9.880  12.463 H562 L4P 140 
L4P H561 1H56 H 0 0 N N N ?      ?      ?      1.225   11.473 12.973 H561 L4P 141 
L4P H572 2H57 H 0 0 N N N ?      ?      ?      1.078   10.697 15.323 H572 L4P 142 
L4P H571 1H57 H 0 0 N N N ?      ?      ?      1.606   9.086  14.849 H571 L4P 143 
L4P H58  H58  H 0 1 N N N ?      ?      ?      3.490   10.326 15.806 H58  L4P 144 
L4P H593 3H59 H 0 0 N N N ?      ?      ?      5.116   10.120 13.947 H593 L4P 145 
L4P H592 2H59 H 0 0 N N N ?      ?      ?      3.981   8.765  13.941 H592 L4P 146 
L4P H591 1H59 H 0 0 N N N ?      ?      ?      3.794   10.079 12.767 H591 L4P 147 
L4P H603 3H60 H 0 0 N N N ?      ?      ?      4.408   12.377 14.682 H603 L4P 148 
L4P H602 2H60 H 0 0 N N N ?      ?      ?      2.976   12.436 13.641 H602 L4P 149 
L4P H601 1H60 H 0 0 N N N ?      ?      ?      2.822   12.662 15.394 H601 L4P 150 
# 
loop_
_chem_comp_bond.comp_id 
_chem_comp_bond.atom_id_1 
_chem_comp_bond.atom_id_2 
_chem_comp_bond.value_order 
_chem_comp_bond.pdbx_aromatic_flag 
_chem_comp_bond.pdbx_stereo_config 
_chem_comp_bond.pdbx_ordinal 
L4P C1  C2   SING N N 1   
L4P C1  O1   SING N N 2   
L4P C1  H12  SING N N 3   
L4P C1  H11  SING N N 4   
L4P C2  C3   SING N N 5   
L4P C2  O2   SING N N 6   
L4P C2  H2   SING N N 7   
L4P C3  O3   SING N N 8   
L4P C3  H32  SING N N 9   
L4P C3  H31  SING N N 10  
L4P C4  C5   SING N N 11  
L4P C4  O4   SING N N 12  
L4P C4  H42  SING N N 13  
L4P C4  H41  SING N N 14  
L4P C5  C6   SING N N 15  
L4P C5  O5   SING N N 16  
L4P C5  H5   SING N N 17  
L4P C6  O6   SING N N 18  
L4P C6  H62  SING N N 19  
L4P C6  H61  SING N N 20  
L4P O1  C11  SING N N 21  
L4P O2  C41  SING N N 22  
L4P O3  P1   SING N N 23  
L4P O4  P1   SING N N 24  
L4P O5  H5O  SING N N 25  
L4P O6  H6O  SING N N 26  
L4P O1P P1   DOUB N N 27  
L4P O2P P1   SING N N 28  
L4P O2P HOP2 SING N N 29  
L4P C11 C12  SING N N 30  
L4P C11 H112 SING N N 31  
L4P C11 H111 SING N N 32  
L4P C12 C13  SING N N 33  
L4P C12 H122 SING N N 34  
L4P C12 H121 SING N N 35  
L4P C13 C14  SING N N 36  
L4P C13 C15  SING N N 37  
L4P C13 H13  SING N N 38  
L4P C14 H143 SING N N 39  
L4P C14 H142 SING N N 40  
L4P C14 H141 SING N N 41  
L4P C15 C16  SING N N 42  
L4P C15 H152 SING N N 43  
L4P C15 H151 SING N N 44  
L4P C16 C17  SING N N 45  
L4P C16 H162 SING N N 46  
L4P C16 H161 SING N N 47  
L4P C17 C18  SING N N 48  
L4P C17 H172 SING N N 49  
L4P C17 H171 SING N N 50  
L4P C18 C19  SING N N 51  
L4P C18 C20  SING N N 52  
L4P C18 H18  SING N N 53  
L4P C19 H193 SING N N 54  
L4P C19 H192 SING N N 55  
L4P C19 H191 SING N N 56  
L4P C20 C21  SING N N 57  
L4P C20 H202 SING N N 58  
L4P C20 H201 SING N N 59  
L4P C21 C22  SING N N 60  
L4P C21 H212 SING N N 61  
L4P C21 H211 SING N N 62  
L4P C22 C23  SING N N 63  
L4P C22 H222 SING N N 64  
L4P C22 H221 SING N N 65  
L4P C23 C24  SING N N 66  
L4P C23 C25  SING N N 67  
L4P C23 H23  SING N N 68  
L4P C24 H243 SING N N 69  
L4P C24 H242 SING N N 70  
L4P C24 H241 SING N N 71  
L4P C25 C26  SING N N 72  
L4P C25 H252 SING N N 73  
L4P C25 H251 SING N N 74  
L4P C26 C27  SING N N 75  
L4P C26 H262 SING N N 76  
L4P C26 H261 SING N N 77  
L4P C27 C28  SING N N 78  
L4P C27 H272 SING N N 79  
L4P C27 H271 SING N N 80  
L4P C28 C29  SING N N 81  
L4P C28 C30  SING N N 82  
L4P C28 H28  SING N N 83  
L4P C29 H293 SING N N 84  
L4P C29 H292 SING N N 85  
L4P C29 H291 SING N N 86  
L4P C30 H303 SING N N 87  
L4P C30 H302 SING N N 88  
L4P C30 H301 SING N N 89  
L4P C41 C42  SING N N 90  
L4P C41 H412 SING N N 91  
L4P C41 H411 SING N N 92  
L4P C42 C43  SING N N 93  
L4P C42 H422 SING N N 94  
L4P C42 H421 SING N N 95  
L4P C43 C44  SING N N 96  
L4P C43 C45  SING N N 97  
L4P C43 H43  SING N N 98  
L4P C44 H443 SING N N 99  
L4P C44 H442 SING N N 100 
L4P C44 H441 SING N N 101 
L4P C45 C46  SING N N 102 
L4P C45 H452 SING N N 103 
L4P C45 H451 SING N N 104 
L4P C46 C47  SING N N 105 
L4P C46 H462 SING N N 106 
L4P C46 H461 SING N N 107 
L4P C47 C48  SING N N 108 
L4P C47 H472 SING N N 109 
L4P C47 H471 SING N N 110 
L4P C48 C49  SING N N 111 
L4P C48 C50  SING N N 112 
L4P C48 H48  SING N N 113 
L4P C49 H493 SING N N 114 
L4P C49 H492 SING N N 115 
L4P C49 H491 SING N N 116 
L4P C50 C51  SING N N 117 
L4P C50 H502 SING N N 118 
L4P C50 H501 SING N N 119 
L4P C51 C52  SING N N 120 
L4P C51 H512 SING N N 121 
L4P C51 H511 SING N N 122 
L4P C52 C53  SING N N 123 
L4P C52 H522 SING N N 124 
L4P C52 H521 SING N N 125 
L4P C53 C54  SING N N 126 
L4P C53 C55  SING N N 127 
L4P C53 H53  SING N N 128 
L4P C54 H543 SING N N 129 
L4P C54 H542 SING N N 130 
L4P C54 H541 SING N N 131 
L4P C55 C56  SING N N 132 
L4P C55 H552 SING N N 133 
L4P C55 H551 SING N N 134 
L4P C56 C57  SING N N 135 
L4P C56 H562 SING N N 136 
L4P C56 H561 SING N N 137 
L4P C57 C58  SING N N 138 
L4P C57 H572 SING N N 139 
L4P C57 H571 SING N N 140 
L4P C58 C59  SING N N 141 
L4P C58 C60  SING N N 142 
L4P C58 H58  SING N N 143 
L4P C59 H593 SING N N 144 
L4P C59 H592 SING N N 145 
L4P C59 H591 SING N N 146 
L4P C60 H603 SING N N 147 
L4P C60 H602 SING N N 148 
L4P C60 H601 SING N N 149 
# 
loop_
_pdbx_chem_comp_descriptor.comp_id 
_pdbx_chem_comp_descriptor.type 
_pdbx_chem_comp_descriptor.program 
_pdbx_chem_comp_descriptor.program_version 
_pdbx_chem_comp_descriptor.descriptor 
L4P SMILES           ACDLabs              10.04 O=P(O)(OCC(O)CO)OCC(OCCC(CCCC(C)CCCC(C)CCCC(C)C)C)COCCC(C)CCCC(C)CCCC(C)CCCC(C)C 
L4P InChI            InChI                1.02b 
InChI=1/C46H95O8P/c1-37(2)17-11-19-39(5)21-13-23-41(7)25-15-27-43(9)29-31-51-35-46(36-54-55(49,50)53-34-45(48)33-47)52-32-30-44(10)28-16-26-42(8)24-14-22-40(6)20-12-18-38(3)4/h37-48H,11-36H2,1-10H3,(H,49,50)/t39-,40?,41-,42?,43-,44-,45-,46+/m1/s1/f/h49H 
L4P InChIKey         InChI                1.02b AFYVWQWWQKSZEV-NPHGDKHVDQ 
L4P SMILES_CANONICAL CACTVS               3.341 CC(C)CCC[C@@H](C)CCC[C@@H](C)CCC[C@@H](C)CCOC[C@@H](CO[P@@](O)(=O)OC[C@H](O)CO)OCC[C@H](C)CCCC(C)CCCC(C)CCCC(C)C 
L4P SMILES           CACTVS               3.341 CC(C)CCC[CH](C)CCC[CH](C)CCC[CH](C)CCOC[CH](CO[P](O)(=O)OC[CH](O)CO)OCC[CH](C)CCCC(C)CCCC(C)CCCC(C)C 
L4P SMILES_CANONICAL "OpenEye OEToolkits" 1.5.0 CC(C)CCC[C@@H](C)CCC[C@@H](C)CCC[C@@H](C)CCOC[C@@H](CO[P@](=O)(O)OC[C@@H](CO)O)OCC[C@H](C)CCC[C@H](C)CCC[C@H](C)CCCC(C)C 
L4P SMILES           "OpenEye OEToolkits" 1.5.0 CC(C)CCCC(C)CCCC(C)CCCC(C)CCOCC(COP(=O)(O)OCC(CO)O)OCCC(C)CCCC(C)CCCC(C)CCCC(C)C 
# 
loop_
_pdbx_chem_comp_identifier.comp_id 
_pdbx_chem_comp_identifier.type 
_pdbx_chem_comp_identifier.program 
_pdbx_chem_comp_identifier.program_version 
_pdbx_chem_comp_identifier.identifier 
L4P "SYSTEMATIC NAME" ACDLabs              10.04 "(2R)-2,3-dihydroxypropyl (2S)-2-{[(3R)-3,7,11,15-tetramethylhexadecyl]oxy}-3-{[(3R,7R,11R)-3,7,11,15-tetramethylhexadecyl]oxy}propyl hydrogen (R)-phosphate" 
L4P "SYSTEMATIC NAME" "OpenEye OEToolkits" 1.5.0 "[(2S)-2,3-bis[(3R,7R,11R)-3,7,11,15-tetramethylhexadecoxy]propyl] [(2R)-2,3-dihydroxypropyl] hydrogen phosphate"                                             
# 
